Acetylation and formylation of alcohols with triphenylphosphine and carbon tetrabromide in ethyl acetate or ethyl formate

被引：59

作者：

Hagiwara, H

Morohashi, K

Sakai, H

Suzuki, T

Ando, M

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 95021, Japan

[2] Niigata Univ, Fac Engn, Niigata 95021, Japan

来源：

TETRAHEDRON | 1998年 / 54卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(98)00255-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alcohols were acetylated or formylated with triphenylphosphine and carbon tetrabromide in ethyl acetate or ethyl (or methyl) formate at room temperature. THP or TBDMS ether of primary alcohol got converted into formate or acetate under the experimental conditions employed in one pot operation. (C) 1998 Elsevier Science Ltd. All rights reserved.

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收藏

页码：5845 / 5852

页数：8

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