Fluorinations of α-seleno carboxylic acid derivatives with hypervalent (difluoroiodo)toluene

被引：51

作者：

Arrica, MA ^{[1
]}

Wirth, T ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 2005卷 / 02期

关键词：

fluorination; hypervalent iodine; selenides;

D O I：

10.1002/ejoc.200400659

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A very efficient synthesis of (difluoroiodo) toluene avoiding the use of elemental chlorine and elemental fluorine is described. We have fluorinated a series of a-acceptor substituted selenides using (difluoroiodo)toluene. The reactions are usually very clean and under the reaction conditions no further oxidized products are observed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：395 / 403

页数：9

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