Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries

被引:256
作者
Choi, Nam-Soon [1 ]
Han, Jung-Gu [1 ]
Ha, Se-Young [1 ]
Park, Inbok [1 ]
Back, Chang-Keun [2 ]
机构
[1] Ulsan Natl Inst Sci & Technol, Sch Energy & Chem Engn, Ulsan 689798, South Korea
[2] Hanwha Chem Co Ltd, Cent R&D Ctr, Daejeoun City 305350, South Korea
基金
新加坡国家研究基金会;
关键词
SULFONE-BASED ELECTROLYTES; DENSITY-FUNCTIONAL THEORY; LI-ION; VINYLENE CARBONATE; LINI0.5MN1.5O4; CATHODES; CYCLING PERFORMANCE; METHYLENE METHANEDISULFONATE; ELECTROCHEMICAL PERFORMANCE; TRIS(TRIMETHYLSILYL) BORATE; LIPF6-BASED ELECTROLYTES;
D O I
10.1039/c4ra11575a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.
引用
收藏
页码:2732 / 2748
页数:17
相关论文
共 118 条
[111]   Effects of Al substitution for Ni and Mn on the electrochemical properties of LiNi0.5Mn1.5O4 [J].
Zhong, G. B. ;
Wang, Y. Y. ;
Zhang, Z. C. ;
Chen, C. H. .
ELECTROCHIMICA ACTA, 2011, 56 (18) :6554-6561
[112]   Electrolyte additive combinations that enhance performance of high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-graphite cells [J].
Zhu, Ye ;
Li, Yan ;
Bettge, Martin ;
Abraham, Daniel P. .
ELECTROCHIMICA ACTA, 2013, 110 :191-199
[113]   Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries [J].
Zhu, Ye ;
Casselman, Matthew D. ;
Li, Yan ;
Wei, Alexander ;
Abraham, Daniel P. .
JOURNAL OF POWER SOURCES, 2014, 246 :184-191
[114]   Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells [J].
Zhu, Ye ;
Li, Yan ;
Bettge, Martin ;
Abraham, Daniel P. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (12) :A2109-A2117
[115]   Study of SEI layer formed on graphite anodes in PC/LiBOB electrolyte using IR spectroscopy [J].
Zhuang, GV ;
Xu, K ;
Jow, TR ;
Ross, PN .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (08) :A224-A227
[116]   Improvement of the thermal stability of LiMn2O4/graphite cells with methylene methanedisulfonate as electrolyte additive [J].
Zuo, Xiaoxi ;
Wu, Junhua ;
Fan, Chengjie ;
Lai, Ke ;
Liu, Jiansheng ;
Nan, Junmin .
ELECTROCHIMICA ACTA, 2014, 130 :778-784
[117]   Effect of tris(trimethylsilyl)borate on the high voltage capacity retention of LiNi0.5Co0.2Mn0.3O2/graphite cells [J].
Zuo, Xiaoxi ;
Fan, Chengjie ;
Liu, Jiansheng ;
Xiao, Xin ;
Wu, Junhua ;
Nan, Junmin .
JOURNAL OF POWER SOURCES, 2013, 229 :308-312
[118]   High-voltage performance of LiCoO2/graphite batteries with methylene methanedisulfonate as electrolyte additive [J].
Zuo, Xiaoxi ;
Fan, Chengjie ;
Xiao, Xin ;
Liu, Jiansheng ;
Nan, Junmin .
JOURNAL OF POWER SOURCES, 2012, 219 :94-99