Communication of electronic information over nanometer distances with supramolecular transduction. An experimental and density functional investigation
被引:11
作者:
Deans, R
论文数: 0引用数: 0
h-index: 0
机构:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USAUniv Massachusetts, Dept Chem, Amherst, MA 01003 USA
Deans, R
[1
]
Cuello, AO
论文数: 0引用数: 0
h-index: 0
机构:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USAUniv Massachusetts, Dept Chem, Amherst, MA 01003 USA
Cuello, AO
[1
]
Galow, TH
论文数: 0引用数: 0
h-index: 0
机构:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USAUniv Massachusetts, Dept Chem, Amherst, MA 01003 USA
Galow, TH
[1
]
Ober, M
论文数: 0引用数: 0
h-index: 0
机构:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USAUniv Massachusetts, Dept Chem, Amherst, MA 01003 USA
Ober, M
[1
]
Rotello, VM
论文数: 0引用数: 0
h-index: 0
机构:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USAUniv Massachusetts, Dept Chem, Amherst, MA 01003 USA
Rotello, VM
[1
]
机构:
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
来源:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
|
2000年
/
07期
关键词:
D O I:
10.1039/a909634e
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
We have synthesized a family of conjugated diaminotriazine-functionalized receptors. Variation of distal functionality modulated the affinity of these receptors for flavin, demonstrating efficient electronic communication over a distance of 11 Angstrom. The origin of this communication was explored using DFT methodology. These calculations demonstrate that modulation of recognition in these systems is derived from a complex push-pull type mechanism.