NCHU-3: A crystalline inorganic-organic hybrid molecular sieve with extra-large cages

被引：29

作者：

Cheng, CY

Fu, SJ

Yang, CJ

Chen, WH

Lin, KJ ^{[1
]}

Lee, GH

Wang, Y

机构：

[1] Natl Chung Hsing Univ, Nanoctr, Dept Chem, Taichung 402, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 17期

关键词：

gallium; hydrothermal synthesis; intercalations; microporous materials; vanadium;

D O I：

10.1002/anie.200250544

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Chinese-vaselike cage, depicted, is contained within the crystalline nanoporous [Ga2(VO)3K2(OH2)3 (C2H4P2O6)4- (H2O)13] structure, NCHU-3, and is thermally stable up to 550°C. NCHU-3 exhibits a highly reversible lithium-ion-intercalation and de-intercalation cycle between +3 and +5 volts. Such cyclability is a key aspect of rechargeable lithium battery cathode materials.

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页码：1937 / 1940

页数：4

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