Synthesis of the core bicyclic system of hyperforin and nemorosone

被引：55

作者：

Kraus, GA ^{[1
]}

Nguyen, TH ^{[1
]}

Jeon, I ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(02)02693-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A direct synthesis of analogs of hyperforin and nemorosone containing the key bicyclic unit was accomplished from 2-carboxyethylcyclohexanone and benzoylcyclohexanone. Key steps included a manganic acetate-mediated cyclization and the formation of the beta-bromo enone. (C) 2003 Published by Elsevier Science Ltd.

引用

页码：659 / 661

页数：3

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