Mechanistic Insights from Isotopic Studies of Glucose Conversion to Aromatics Over ZSM-5

被引：123

作者：

Carlson, Torren R. ^{[2
]}

Jae, Jungho ^{[2
]}

Huber, George W. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem Engn, Goessmann Lab 159, Amherst, MA 01003 USA

[2] Univ Massachusetts, Goessmann Lab 211, Amherst, MA 01003 USA

来源：

CHEMCATCHEM | 2009年 / 1卷 / 01期

基金：

美国国家科学基金会;

关键词：

aromaticity; biomass; heterogeneous catalysis; isotopic labeling; zeolites; FAST PYROLYSIS; BED REACTOR; BIOMASS PYROLYSIS; CATALYSTS; METHANOL; ZEOLITE; HYDROCARBONS; OPPORTUNITIES; GASOLINE; LIQUIDS;

D O I：

10.1002/cctc.200900130

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fast and the furanose: Catalytic fast pyrolysis is a promising new route for the production of aromatics from biomass. However, little is known about the chemistry occurring within the catalyst. Through isotopic labeling studies, insights into controlling the chemistry of catalytic fast pyrolysis are revealed. © 2009 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

引用

页码：107 / 110

页数：4

共 27 条

[1] PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .1. CONVERSION OVER VARIOUS CATALYSTS [J].

ADJAYE, JD ;

BAKHSHI, NN .

FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :161-183

[2] Catalytic pyrolysis of woody biomass in a fluidized bed reactor:: Influence of the zeolite structure [J].

Aho, A. ;

Kumar, N. ;

Eranen, K. ;

Salmi, T. ;

Hupa, M. ;

Murzin, D. Yu. .

FUEL, 2008, 87 (12) :2493-2501

[3]

AHO A, 2008, KOTA PROM STI, P49

[4] Isotopic tracer studies of propane reactions on H-ZSM5 zeolite [J].

Biscardi, JA ;

Iglesia, E .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (46) :9284-9289

[5] Reaction pathways and rate-determining steps in reactions of alkanes on H-ZSM5 and Zn/H-ZSM5 catalysts [J].

Biscardi, JA ;

Iglesia, E .

JOURNAL OF CATALYSIS, 1999, 182 (01) :117-128

[6] Conversion of methanol to hydrocarbons over zeolite H-ZSM-5: On the origin of the olefinic species [J].

Bjorgen, Morten ;

Svelle, Stian ;

Joensen, Finn ;

Nerlov, Jesper ;

Kolboe, Stein ;

Bonino, Francesca ;

Palumbo, Luisa ;

Bordiga, Silvia ;

Olsbye, Unni .

JOURNAL OF CATALYSIS, 2007, 249 (02) :195-207

[7] OPPORTUNITIES FOR BIOMASS PYROLYSIS LIQUIDS PRODUCTION AND UPGRADING [J].

BRIDGWATER, AV ;

COTTAM, ML .

ENERGY & FUELS, 1992, 6 (02) :113-120

[8] Green gasoline by catalytic fast pyrolysis of solid biomass derived compounds [J].

Carlson, Torren R. ;

Vispute, Tushar R. ;

Huber, George W. .

CHEMSUSCHEM, 2008, 1 (05) :397-400

[9]

CHEN NY, 1986, CHEMTECH, V16, P506

[10]

Dao L.H., 1987, Pap. Amer. Chem. Soc. Div. Fuel Chem, V32, P308

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