Hydrotris(indazolyl)borate, Tp4Bo a surprisingly effective Tp ligand for supramolecular assembly

被引：50

作者：

Janiak, C

Temizdemir, S

Dechert, S

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Tech Univ Berlin, Inst Anorgan & Analyt Chem, D-10623 Berlin, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 06期

关键词：

crystal structures; pi-pi interactions; framework structures; indazolylborate ligand; transition metal complexes; supramolecular assembly;

D O I：

10.1016/S1387-7003(00)00063-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The assembly of T1Tp(4Bo) and M(Tp(4Bo))(2) (M e.g. Co, Ni) in the crystal is dictated by aromatic pi-pi and C-H ...pi interactions. This leads to the formation of chiral C-2-symmetrical pairs (for T1) or solvent-filled, about 30%-porous, non-covalent framework structures (for Co and Ni). The potassium salt KTp(4Bo) features a kappa N,eta-C-C,eta(2)-C-N cation-pi coordination mode - curious for a Tp-type ligand. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：271 / 275

页数：5