Novel monolabeled redox biomaterials: Amino-ended poly(ethylene oxide) ferrocenes and their biotin-conjugates

被引:13
作者
Anne, A [1 ]
机构
[1] Univ Denis Diderot, CNRS, Electrochim Mol Lab, F-75251 Paris 05, France
关键词
D O I
10.1016/S0040-4039(97)10686-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Treatment of ferrocenoyl chloride with symmetrical poly(oxyalkylene) diamine 1 in excess affords the monofonctionalized derivative 2 in moderate to good yields. This one-step procedure provides a convenient entry to novel monolabeled redox precursors such as the biotin derivative 3 for more elaborate architectures. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:561 / 564
页数:4
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