Synthesis and reactivity of a mononuclear parent amido nickel complex.: Structures of Ni[C6H3-2,6-(CH2PiPr2)2](NH2) and Ni[C6H3-2,6-(CH2PiPr2)2](OMe)

被引：78

作者：

Cámpora, J ^{[1
]}

Palma, P ^{[1
]}

del Río, D ^{[1
]}

Conejo, MM ^{[1
]}

Alvarez, E ^{[1
]}

机构：

[1] Univ Seville, Consejo Super Invest Cient, Inst Invest Quim, Seville 41092, Spain

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 24期

关键词：

D O I：

10.1021/om049312r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of a nickel parent amido complex, Ni(PCP)(NH2), has been synthesized and structurally characterized. This compound reacts quantitatively with water and methanol to give the mononuclear hydroxide and methoxide derivatives Ni(PCP)(OH) and Ni(PCP)(OMe). Ni(PCP)(NH2) behaves as a strong nucleophile and adds rapidly to benzaldehyde, affording an equimolecular mixture of the aldimido derivative Ni(PCP)(N=CHPh), the hydroxide Ni(PCP)(OH), and ammonia.

引用

页码：5653 / 5655

页数：3

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