The hybrid open-framework of tin(II) phosphonopropionate oxalate, Sn4(O3PCH2CH2CO2)2(C2O4)

被引:90
作者
Stock, N
Stucky, GD
Cheetham, AK [1 ]
机构
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
关键词
D O I
10.1039/b006511k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrothermal synthesis and single crystal XRD characterization of a three-dimensional open-framework tin(II) phosphonopropionate oxalate, Sn-4(O3PCH2CH2CO2)(2)-(C2O4), is described; the structure contains two different bifunctional linkers as well as SnO3 and SnO4 polyhedra each with a stereochemically active lone pair of electrons, and exhibits several types of channels.
引用
收藏
页码:2277 / 2278
页数:2
相关论文
共 29 条
[1]   Synthesis and structural characterization of a novel tin(II) phosphonate, Sn2(O3PCH3)(C2O4) [J].
Adair, B ;
Natarajan, S ;
Cheetham, AK .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (06) :1477-1479
[2]   Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2 [J].
Ayyappan, S ;
de Delgado, GD ;
Cheetham, AK ;
Férey, G ;
Rao, CNR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17) :2905-+
[3]  
*BRUK AXS, 1998, SHELXTL XRAY CRYST A
[4]  
BUJOLI B, 1992, EUR J SOL STATE INOR, V29, P171
[5]   SYNTHESIS OF LAYERED ZR(O3PCH2CH2COCL)2 FROM ZR(O3PCH2CH2COOH)2 [J].
BURWELL, DA ;
THOMPSON, ME .
CHEMISTRY OF MATERIALS, 1991, 3 (01) :14-17
[6]   STRUCTURAL STUDIES OF ORIENTED ZIRCONIUM BIS(PHOSPHONOACETIC ACID) USING SOLID-STATE P-31 AND C-13 NMR [J].
BURWELL, DA ;
VALENTINE, KG ;
TIMMERMANS, JH ;
THOMPSON, ME .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4144-4150
[7]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[8]  
2-U
[9]   A hybrid open-framework iron phosphate-oxalate with a large unidimensional channel, showing reversible hydration [J].
Choudhury, A ;
Natarajan, S ;
Rao, CNR .
CHEMISTRY OF MATERIALS, 1999, 11 (09) :2316-+
[10]   Hybrid framework iron(II) phosphate-oxalates [J].
Choudhury, A ;
Natarajan, S ;
Rao, CNR .
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 146 (02) :538-545