Seed-mediated growth and properties of copper nanoparticles, nanoparticle 1D arrays and nanorods

被引:34
作者
Liu, CM
Guo, L [1 ]
Xu, HB
Wu, ZY
Weber, J
机构
[1] Beihang Univ, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China
[3] Tech Univ Dresden, Inst Low Temp Phys, D-001062 Dresden, Germany
关键词
seed-mediated growth; soft template; UV luminescence; XANES;
D O I
10.1016/S0167-9317(03)00033-9
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Copper nanorods were simply prepared by a method of seed-mediated growth in solution. In this method, poly(N-vinyl-2-pyrrolidone) (PVP) was used as a surface modified reagent as well as a soft template. By adjusting the concentration of copper ion and PVP and the refluxing time, the copper nanoparticles, copper 1D array nanoparticles wrapped in PVP and nanorods were obtained successively. Transmission electron microscopy, ultraviolet-visible spectrum and fluorescence spectroscopy were used to characterize the as prepared copper nanoparticles and nanorods. X-ray absorption near edge structure (XANES) spectrum was carried out to investigate the microstructure. Obvious UV luminescence was observed for the copper nanorods. The mechanism of the growth process of copper nanomaterials was discussed. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:107 / 114
页数:8
相关论文
共 25 条
[1]   CONDUCTANCE STEPS AND QUANTIZATION IN ATOMIC-SIZE CONTACTS [J].
AGRAIT, N ;
RODRIGO, JG ;
VIEIRA, S .
PHYSICAL REVIEW B, 1993, 47 (18) :12345-12348
[2]   Pure alpha-Fe coated by an Fe1-xBx alloy [J].
Duxin, N ;
Stephan, O ;
Petit, C ;
Bonville, P ;
Colliex, C ;
Pileni, MP .
CHEMISTRY OF MATERIALS, 1997, 9 (10) :2096-2100
[3]  
ELSAYED MA, 2001, ACCOUNTS CHEM RES, V290, P314
[4]   Research of nonlinear optical properties of copper nanoparticles [J].
Guo, L ;
Wu, ZH ;
Ibrahim, K ;
Liu, T ;
Tao, Y ;
Ju, X .
EUROPEAN PHYSICAL JOURNAL D, 1999, 9 (1-4) :591-594
[5]   Formation and absorption spectrum of copper nanoparticles from the radiolytic reduction of Cu(CN)2- [J].
Henglein, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (06) :1206-1211
[6]   Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes [J].
Hu, JT ;
Odom, TW ;
Lieber, CM .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (05) :435-445
[7]   Synthesis, characterization, and nonlinear optical properties of copper nanoparticles [J].
Huang, HH ;
Yan, FQ ;
Kek, YM ;
Chew, CH ;
Xu, GQ ;
Ji, W ;
Oh, PS ;
Tang, SH .
LANGMUIR, 1997, 13 (02) :172-175
[8]  
Jana NR, 2001, ADV MATER, V13, P1389, DOI 10.1002/1521-4095(200109)13:18<1389::AID-ADMA1389>3.0.CO
[9]  
2-F
[10]   Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio [J].
Jana, NR ;
Gearheart, L ;
Murphy, CJ .
CHEMICAL COMMUNICATIONS, 2001, (07) :617-618