Microporous porphyrin and metalloporphyrin materials

被引：78

作者：

Kosal, ME ^{[1
]}

Suslick, KS ^{[1
]}

机构：

[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2000年 / 152卷 / 01期

关键词：

porphyrins; metalloporphyrins; microporous materials; crystal engineering; solid-state networks;

D O I：

10.1006/jssc.2000.8672

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diverse efforts to rationally construct microporous solids using porphyrins and metalloporphyrins as molecular building blocks are reviewed. Porphyrin-based molecular crystals, hydrogen-bonded networks, and metal ion coordination polymer networks are examined in detail. Recurring geometrical motifs observed in the structural frameworks of different porphyrinic solids are emphasized, and the influences of solvates and guest molecules are explored. Attempts to construct porphyrin-siloxane networks are also reviewed. (C) 2000 Academic Press.

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页码：87 / 98

页数：12

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