Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal-group 13 metal bond formation

被引：31

作者：

Steinke, T ^{[1
]}

Gemel, C ^{[1
]}

Cokoja, M ^{[1
]}

Winter, M ^{[1
]}

Fischer, RA ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Inst Anorgan Chem 2, D-44780 Bochum, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 09期

关键词：

D O I：

10.1039/b301928d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Insertion of the carbenoid group 13 metal species InCp* (Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)(3) into the Rh-Cl bonds of[{RhCp*Cl-2}(2)] yields the new complexes [ Cp* Rh( InCp*) 3( Cl) 2] 1 and [Cp*Rh(mu(2)-Cl)(2)(InC(SiMe3)(3))(3)] 2, respectively, exhibiting novel cage-like intermetallic complexes with In-Cl-In bridges.

引用

页码：1066 / 1067

页数：2

共 15 条

[1] (PENTAMETHYLCYCLOPENTADIENYL)INDIUM(I) AND (PENTAMETHYLCYCLOPENTADIENYL)INDIUM(III) COMPOUNDS - SYNTHESES, REACTIVITIES, AND X-RAY-DIFFRACTION AND ELECTRON-DIFFRACTION STUDIES OF IN(C5ME5) [J].

BEACHLEY, OT ;

BLOM, R ;

CHURCHILL, MR ;

FAEGRI, K ;

FETTINGER, JC ;

PAZIK, JC ;

VICTORIANO, L .

ORGANOMETALLICS, 1989, 8 (02) :346-356

[2]

Fischer, 1999, ANGEW CHEM, V111, P3002

[3]

Fischer RA, 1999, ANGEW CHEM INT EDIT, V38, P2831

[4] ORGANOMETALLIC COMPLEXES CONTAINING BONDS BETWEEN TRANSITION-METALS AND GROUP-IIIB METALS [J].

HSIEH, ATT .

INORGANICA CHIMICA ACTA, 1975, 14 (01) :87-104

[5] SYNTHESIS OF COMPLEXES CONTAINING TRANSITION METAL-INDIUM BONDS [J].

HSIEH, ATT ;

MAYS, MJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 37 (01) :9-&

[6] INTERACTION OF INDIUM(I) HALIDES WITH ORGANOMETALLIC COMPLEXES CONTAINING METAL-METAL AND METAL-HALOGEN BONDS [J].

HSIEH, ATT ;

MAYS, MJ .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1971, 7 (03) :223-&

[7] IONIC DISSOCIATION OF PENTACARBONYLMANGANESE-INDIUM COMPLEXES IN ACEETONITRILE SOLUTION [J].

HSIEH, ATT ;

MAYS, MJ .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (20) :1234-&

[8] Unexpected reactivity of Cp*Ga toward Fe-Cl bonds:: Synthesis and structure of Cp*(Cp*Ga)2FeGaCl2•THF and of Cp*(CO)2FeGa(η2-Cp*)Cl [J].

Jutzi, P ;

Neumann, B ;

Schebaum, LO ;

Stammler, A ;

Stammler, HG .

ORGANOMETALLICS, 2000, 19 (07) :1445-1447

[9] Lewis acid-base adducts of pentamethylcyclopentadienylgallium with trivalent group 13-element compounds [J].

Jutzi, P ;

Neumann, B ;

Reumann, G ;

Schebaum, LO ;

Stammler, HG .

ORGANOMETALLICS, 2001, 20 (13) :2854-2858

[10] PENTAMETHYLCYCLOPENTADIENYLRHODIUM AND -IRIDIUM HALIDES .I. SYNTHESIS AND PROPERTIES [J].

KANG, JW ;

MOSELEY, K ;

MAITLIS, PM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (22) :5970-&

← 1 2 →