[MoO2Cl2] as catalyst for hydrosilylation of aldehydes and ketones

被引:121
作者
Fernandes, AC [1 ]
Fernandes, R [1 ]
Romao, CC [1 ]
Royo, B [1 ]
机构
[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, EAN, P-2781901 Oeiras, Portugal
关键词
D O I
10.1039/b414145h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The high valent molybdenum-dioxo complex [MoO2Cl2] catalyzes the addition of dimethylphenylsilane to aldehydes and ketones to afford the corresponding dimethylphenylsilyl ethers in quantitative yield.
引用
收藏
页码:213 / 214
页数:2
相关论文
共 11 条
[1]   REACTIONS OF CHLOROSILANES WITH DIOXOMOLYBDENUM(VI) COMPLEXES [J].
ARZOUMANIAN, H ;
KRENTZIEN, H ;
CORAO, C ;
LOPEZ, R ;
AGRIFOGLIO, G .
POLYHEDRON, 1995, 14 (20-21) :2887-2891
[2]   Reactions of hydrosilanes with transition-metal complexes: Formation of stable transition-metal silyl compounds [J].
Corey, JY ;
Braddock-Wilking, J .
CHEMICAL REVIEWS, 1999, 99 (01) :175-292
[3]   METAL-CENTERED OXYGEN ATOM TRANSFER-REACTIONS [J].
HOLM, RH .
CHEMICAL REVIEWS, 1987, 87 (06) :1401-1449
[4]   C-H bond activation of hydrocarbons by an imidozirconocene complex [J].
Hoyt, HM ;
Michael, FE ;
Bergman, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (04) :1018-1019
[5]   Reversing the role of the metal-oxygen π-bond.: Chemoselective catalytic reductions with a rhenium(V)-dioxo complex [J].
Kennedy-Smith, JJ ;
Nolin, KA ;
Gunterman, HP ;
Toste, FD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (14) :4056-4057
[6]  
Kühn FE, 2002, CHEM-EUR J, V8, P2370, DOI 10.1002/1521-3765(20020517)8:10<2370::AID-CHEM2370>3.0.CO
[7]  
2-A
[8]  
Parshall G.W., 1992, HOMOGENEOUS CATALYST
[9]   Reactivity of a terminal Ti(IV) imido complex toward alkenes and alkynes: Cycloaddition vs C-H activation [J].
Polse, JL ;
Andersen, RA ;
Bergman, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (51) :13405-13414
[10]   Synthesis, structure, and reactivity of monomeric titanocene sulfido and disulfido complexes. Reaction of H-2 with a terminal M=S bond [J].
Sweeney, ZK ;
Polse, JL ;
Andersen, RA ;
Bergman, RG ;
Kubinec, MG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4543-4544