The selective functionalization of saturated hydrocarbons. Part 42. Further studies in selective phenylselenation.

被引：3

作者：

Barton, DHR ^{[1
]}

Lalic, G ^{[1
]}

Smith, JA ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(97)10397-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An improved procedure for the phenylselenation of saturated hydrocarbons has been developed. The reaction of tributylphosphine with diphenyl diselenide in the presence of Fe-II picolinate in pyridine-acetonitrile-trace of water affords a quantitative yield of phenylselenol. Subsequent or prior addition of the saturated hydrocarbon and final addition of 30% hydrogen peroxide gives phenylselenation in excellent yield based on the oxidant added. The mechanism of this reaction has been further studied; carbon and hydroxyl radicals are not part of the mechanism. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1725 / 1734

页数：10

共 25 条

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