Synthesis and reactivity of hydroxycyclopentadienyl and aminocyclopentadienyl ruthenium alcohol complexes

被引：20

作者：

Casey, CP ^{[1
]}

Vos, TE ^{[1
]}

Bikzhanova, GA ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 05期

关键词：

D O I：

10.1021/om020891e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic aminocyclopentadienyl and hydroxycyclopentadienyl ruthenium alcohol complexes were synthesized from reaction of the corresponding ruthenium chloride with AgBF4 in the presence of an alcohol. Exchange rates of free alcohol with hydroxycyclopentadienyl and aminocyclopentadienyl ruthenium benzyl alcohol complexes were rapid (t(1/2) = 5-10 min) at -47 degreesC.

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页码：901 / 903

页数：3

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