Poly(ethylenedioxythiophene) (PEDOT) as polymer electrode in redox supercapacitor

被引：181

作者：

Ryu, KS ^{[1
]}

Lee, YG ^{[1
]}

Hong, YS ^{[1
]}

Park, YJ ^{[1
]}

Wu, XL ^{[1
]}

Kim, KM ^{[1
]}

Kang, MG ^{[1
]}

Park, NG ^{[1
]}

Chang, SH ^{[1
]}

机构：

[1] ETRI, Power Source Device Team, Taejon 305350, South Korea

来源：

ELECTROCHIMICA ACTA | 2004年 / 50卷 / 2-3期

关键词：

supercapacitor; redox type; hybrid type; conducting polymer; active carbon; poly(ethylenedioxythiophene);

D O I：

10.1016/j.electacta.2004.02.055

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We have fabricated two types of supercapacitors, redox and hybrid, based on poly(ethylenedioxythiophene) (PEDOT) and MSP-20 powder as electrode materials with Et4NBF4 in PC and LiPF6 in EC/DMC as electrolyte solutions. The redox type of supercapacitor is assembled with two PEDOT electrode sheets, while the hybrid type with PEDOT and MSP-20 electrode sheets. Their electrochemical properties in different electrolyte solutions and cut-off voltage range are investigated. From the results of charge and discharge for the hybrid type, the specific discharge capacitance of 56 F/g after 1000th cycle in the range 0-3 V is observed with LiPF6 in EC/DMC system. The electrochemical properties of the hybrid type supercapacitor are shown much better than them of the redox type. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：843 / 847

页数：5

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