Hybrid molecular materials based on organic molecules and the inorganic magnetic cluster [M4(H2O)2(PW9O34)2]10- (M2+ = Co, Mn)

被引:38
作者
Clemente-Leon, M
Coronado, E [1 ]
Galan-Mascaros, JR
Gimenez-Saiz, C
Gomez-Garcia, CJ
Fernandez-Otero, T
机构
[1] Univ Valencia, Dept Quim Inorgan, E-46100 Burjassot, Spain
[2] UPV, Fac Quim, Lab Electroquim, San Sebastian 20080, Spain
关键词
D O I
10.1039/a706864f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis and physical characterization of new organic-inorganic hybrids formed by conducting and magnetic networks are reported. The crystalline radical salts are formed by BEDT-TTF type donors as the organic part, and by large metal-oxide clusters of the type [M-4(H2O)(2)(PW9O34)(2)](10-)(M2+ = Co, Mn) as the inorganic part. We also show how these magnetic clusters can be incorporated in conducting organic polymers to give hybrid organic-inorganic films.
引用
收藏
页码:309 / 312
页数:4
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