Phenylamines as building blocks to layered inorganic-organic structures

被引：39

作者：

Bourne, SA ^{[1
]}

Mangombo, Z ^{[1
]}

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

来源：

CRYSTENGCOMM | 2004年 / 6卷

关键词：

D O I：

10.1039/b406671e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five inorganic-organic layered composites have been prepared and characterised. Copper(II) chloride and lead(II) chloride compounds with 1,4-phenylenediamine and benzidine have a 1: 1 inorganic: organic layer structure. The copper(II) chloride structure with p-biphenylamine is a 1: 2 inorganic: organic layer structure; this compound undergoes an order-disorder transition at ca. 200 K. Crystallisation of benzidine in the presence of lead (II) chloride or cobalt(II) chloride at elevated temperature produced the chloride salt of benzidine.

引用

页码：437 / 442

页数：6

共 16 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189

[3]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[4]

2-Z

[5] Crystal engineering: from weak hydrogen bonds to co-ordination bonds [J].

Biradha, K .

CRYSTENGCOMM, 2003, 5 :374-384

[6]

Desiraju G. R., 1989, DESIGN ORGANIC SOLID

[7] Organic-inorganic hybrid solids:: control of perhalometallate solid state structures [J].

Gillon, AL ;

Lewis, GR ;

Orpen, AG ;

Rotter, S ;

Starbuck, J ;

Wang, XM ;

Rodríguez-Martín, Y ;

Ruiz-Pérez, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3897-3905

[8] Synthesis, structure, and properties of organic-inorganic perovskites and related materials [J].

Mitzi, DB .

PROGRESS IN INORGANIC CHEMISTRY, VOL 48, 1999, 48 :1-121

[9] Templating and structural engineering in organic-inorganic perovskites [J].

Mitzi, DB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (01) :1-12

[10]

Otwinowski Z., 2000, INT TABLES CRYSTALLO, VF

← 1 2 →