Charge storage properties of biopolymer electrodes with (sub)tropical lignins

被引:34
作者
Admassie, Shimelis [1 ,2 ]
Nilsson, Ting Yang [2 ]
Inganas, Olle [2 ]
机构
[1] Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
[2] Univ Addis Ababa, Dept Chem, Addis Ababa, Ethiopia
关键词
SUPERCAPACITOR APPLICATIONS; ENERGY-STORAGE; GRAPHENE; DEVICES; CATHODE;
D O I
10.1039/c4cp03777d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrochemical and charge storage properties of different lignins inside biopolymer electrodes were studied and correlated with the chemical variations of the lignins as indicated from the nuclear magnetic resonance (NMR) spectroscopic data. The varying fractions of monolignols were found to correlate with charge storage properties. It was found that as the sinapyl to guaiacyl (S/G) ratio increased both the specific capacitance and charge capacity increased considerably. This indicates that quinones generated on S-units can contribute more to charge storage in the biopolymer electrodes.
引用
收藏
页码:24681 / 24684
页数:4
相关论文
共 20 条
[1]   A renewable biopolymer cathode with multivalent metal ions for enhanced charge storage [J].
Admassie, Shimelis ;
Elfwing, Anders ;
Jager, Edwin W. H. ;
Bao, Qinye ;
Inganas, Olle .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (06) :1974-1979
[2]  
[Anonymous], 2010, ADV CHEM SER
[3]   Graphene for energy conversion and storage in fuel cells and supercapacitors [J].
Choi, Hyun-Jung ;
Jung, Sun-Min ;
Seo, Jeong-Min ;
Chang, Dong Wook ;
Dai, Liming ;
Baek, Jong-Beom .
NANO ENERGY, 2012, 1 (04) :534-551
[4]   Copper and cadmium sorption onto kraft and organosolv lignins [J].
Harmita, Hengky ;
Karthikeyan, K. G. ;
Pan, XueJun .
BIORESOURCE TECHNOLOGY, 2009, 100 (24) :6183-6191
[5]   Graphene nanosheets-poly(o-aminophenol) nanocomposite for supercapacitor applications [J].
Heli, H. ;
Yadegari, H. ;
Jabbari, A. .
MATERIALS CHEMISTRY AND PHYSICS, 2012, 134 (01) :21-25
[6]   An Overview of the Applications of Graphene-Based Materials in Supercapacitors [J].
Huang, Yi ;
Liang, Jiajie ;
Chen, Yongsheng .
SMALL, 2012, 8 (12) :1805-1834
[7]   25th Anniversary Article: Organic Photovoltaic Modules and Biopolymer Supercapacitors for Supply of Renewable Electricity: A Perspective from Africa [J].
Inganas, Olle ;
Admassie, Shimelis .
ADVANCED MATERIALS, 2014, 26 (06) :830-847
[8]   Poly(p-phenylenediamine)/graphene nanocomposites for supercapacitor applications [J].
Jaidev ;
Ramaprabhu, S. .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (36) :18775-18783
[9]   Heterogeneous nanostructured electrode materials for electrochemical energy storage [J].
Liu, Ran ;
Duay, Jonathon ;
Lee, Sang Bok .
CHEMICAL COMMUNICATIONS, 2011, 47 (05) :1384-1404
[10]   Recent Advances in Conjugated Polymer Energy Storage [J].
Mike, Jared F. ;
Lutkenhaus, Jodie L. .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2013, 51 (07) :468-480