Lipase catalysed synthesis of aliphatic, terpene and aromatic esters by alcoholysis in solvent-free medium

被引：27

作者：

Gryglewicz, S ^{[1
]}

Jadownicka, E ^{[1
]}

Czerniak, A ^{[1
]}

机构：

[1] Wroclaw Univ Technol, Dept Chem, PL-50344 Wroclaw, Poland

来源：

BIOTECHNOLOGY LETTERS | 2000年 / 22卷 / 17期

关键词：

biosynthesis of esters; lipase; transesterification;

D O I：

10.1023/A:1005600631600

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Biosynthesis of pentyl and terpene valerates, terpene acetates, hexyl and benzyl benzoates was conducted via alcoholysis, at 55 degrees C, in a solvent-free medium, using lipases from Candida antarctica and Mucor miehei as catalysts. The yield higher than 90% was achieved (Candida antarctica) after 10 h for synthesis of pentyl valerate and 3-methylbutyl valerate, 35 h for 2-methylbytyl valerate, 6 h for geranyl and cytronelyl acetates, 10 h for geranyl and cytronelyl valerates, 75 h for hexyl benzoate and 100 h for benzyl benzoate.

引用

页码：1379 / 1382

页数：4

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