A novel synthesis of functionalised tertiary phosphines by palladium catalysed phosphination with triarylphosphines

被引：47

作者：

Kwong, FY ^{[1
]}

Lai, CW ^{[1
]}

Tian, Y ^{[1
]}

Chan, KS ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)01850-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium catalysed Pd-aryl/P-aryl exchange was applied in the synthesis of various functionalised phosphines from their corresponding substituted aryl triflates using triarylphosphines as the phosphinating agents. This method tolerated many functional groups including ketone, aldehyde, ester, nitrile, methyl ether, pyridyl and chloride groups. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：10285 / 10289

页数：5

共 33 条

[1] AEXANDROVICH PS, Patent No. 4837394
[2] Convenient and direct preparation of tertiary phosphines via nickel-catalysed cross-coupling
Ager, DJ
East, MB
Eisenstadt, A
Laneman, SA
[J]. CHEMICAL COMMUNICATIONS, 1997, (24) : 2359 - 2360
[3] EVIDENCE OF THE FORMATION OF ZEROVALENT PALLADIUM FROM PD(OAC)2 AND TRIPHENYLPHOSPHINE
AMATORE, C
JUTAND, A
MBARKI, MA
[J]. ORGANOMETALLICS, 1992, 11 (09) : 3009 - 3013
[4] Novel concepts in directed biaryl synthesis - Part 69 - Palladium-mediated intramolecular acylation reaction in the attempted phosphinylation of a sterically hindered trifluoromethylsulfonyloxybiaryl carboxylic ester
Bringmann, G
Wuzik, A
Vedder, C
Pfeiffer, M
Stalke, D
[J]. CHEMICAL COMMUNICATIONS, 1998, (11) : 1211 - 1212
[5] SYNTHESIS OF CHIRAL 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) VIA A NOVEL NICKEL-CATALYZED PHOSPHINE INSERTION
CAI, DW
PAYACK, JF
BENDER, DR
HUGHES, DL
VERHOEVEN, TR
REIDER, PJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (23) : 7180 - 7181
[6] Cai DW, 1999, ORG SYNTH, V76, P6
[7] N-PHENYL-P,P,P-TRIARYLPHOSPHA-LAMBDA-5-AZENES, TRIARYLPHOSPHINES, AND TRIARYLPHOSPHINE OXIDES - SUBSTITUENT EFFECTS ON N-15, P-13, AND C-13 NMR-SPECTRA
CHOU, WN
POMERANTZ, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (08) : 2762 - 2769
[8] Ding KL, 1999, CHEM-EUR J, V5, P1734, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1734::AID-CHEM1734>3.3.CO
[9] 2-7
[10] Franciò G, 2000, ANGEW CHEM INT EDIT, V39, P1428, DOI 10.1002/(SICI)1521-3773(20000417)39:8<1428::AID-ANIE1428>3.0.CO

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