Cavity-induced spin-spin interaction between organic radicals within a self-assembled coordination cage

被引：75

作者：

Nakabayashi, K

Kawano, M ^{[1
]}

Yoshizawa, M

Ohkoshi, S

Fujita, M

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Sci & Technol Agcy, JST, CREST, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 51期

关键词：

D O I：

10.1021/ja044445p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a new approach for manipulating spin-spin interaction by the self-assembled M6L4-coordination cage. Stable radicals are encapsulated by the cage to become a radical pair in triplet state in both solid and solution states, although the radicals themselves show doublet character without particular intermolecular interaction in solution. These results were confirmed by ESR spectroscopy and X-ray crystallography. Copyright © 2004 American Chemical Society.

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页码：16694 / 16695

页数：2

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