Regio- and stereoselective oxyfunctionalization at C-1 and C-5 in sesquiterpene guaianolides

被引：27

作者：

Bargues, V ^{[1
]}

Blay, G ^{[1
]}

Cardona, L ^{[1
]}

García, B ^{[1
]}

Pedro, JR ^{[1
]}

机构：

[1] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Valencia, Spain

来源：

TETRAHEDRON | 1998年 / 54卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(97)10392-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regio- and stereoselective functionalization at C-1 and C-5 positions in a guaiane skeleton by allylic hydroxylation are described The stereochemistry of the resulting compounds are identical to those of the majority of natural 1- and 5-hydroxy-guaianolides. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1845 / 1852

页数：8

共 31 条

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