STUDIES ON THE SYNTHESIS OF SESQUITERPENE LACTONES .16. THE SYNTHESES OF 11-BETA,13-DIHYDROKAUNIOLIDE, ESTAFIATIN, ISODEHYDROCOSTUSLACTONE, 2-OXODESOXYLIGUSTRIN, ARBORESCIN, 1,10-EPIARBORESCIN, 11-BETA,13-DIHYDROLUDARTIN, 8-DEOXY-11-BETA,13-DIHYDRORUPICOLIN-B, 8-DEOXYRUPICOLIN-B, 3,4-EPILUDARTIN, LUDARTIN, KAUNIOLIDE, DEHYDROLEUCODIN, AND LEUCODIN

被引：35

作者：

ANDO, M ^{[1
]}

IBAYASHI, K ^{[1
]}

MINAMI, N ^{[1
]}

YOSHIMURA, H ^{[1
]}

NAKAMURA, T ^{[1
]}

ISOGAI, K ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF NATURAL PRODUCTS | 1994年 / 57卷 / 04期

关键词：

D O I：

10.1021/np50106a001

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

A total of eleven naturally occurring guaianolides, 11 beta,13-dihydrokauniolide, estafiatin, isodehydrocostuslactone, 2-oxodesoxyligustrin, arborescin, 11 beta,13-dihydroludattin, 8-deoxy-11 beta,13-dihydrorupicolin B, ludartin, kauniolide, dehydroleucodin, and leucodin, and three related compounds, 1,10-epiarborescin, 8-deoxyrupicolin B, and 3,4-epiludartin, were synthesized through a common cationic intermediate A, which was derived from (11S)-1 beta-(mesyloxy)eudesm-3-eno-12,6 alpha-lactone [2] by solvolytic rearrangement.

引用

页码：433 / 445

页数：13

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