Blue-emitting type-II semiconductor nanocrystals with high efficiency prepared by aqueous method

被引:8
作者
Li, Chunliang
Nishikawa, Kazuhiro
Ando, Masanori
Enomoto, Hiroyuki
Murase, Norio [1 ]
机构
[1] AIST, Photon Res Inst, Ikeda, Osaka 5638577, Japan
[2] Osaka Electrocommun Univ, Grad Sch Engn, Div Elect & Appl Phys, Neyagawa, Osaka 5728530, Japan
关键词
D O I
10.1246/cl.2007.438
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Forming a type-II structure on alloyed ZnSe core through a facile aqueous method using Cd and S ions resulted in nanocrystals with a photoluminescence wavelength adjusted to the blue region. Their surface was additionally coated by wider bandgap ZnS shell through photodecomposition of the surfactant molecules. Optimizing the conditions for creating the core and shells increased their emission efficiency more than 40%.
引用
收藏
页码:438 / 439
页数:2
相关论文
共 18 条
[1]   Quantum dot bioconjugates for ultrasensitive nonisotopic detection [J].
Chan, WCW ;
Nie, SM .
SCIENCE, 1998, 281 (5385) :2016-2018
[2]   Electroluminescence from single monolayers of nanocrystals in molecular organic devices [J].
Coe, S ;
Woo, WK ;
Bawendi, M ;
Bulovic, V .
NATURE, 2002, 420 (6917) :800-803
[3]  
COLVIN VL, 1994, NATURE, V370, P354, DOI 10.1038/370354a0
[4]   (CdSe)ZnS core-shell quantum dots: Synthesis and characterization of a size series of highly luminescent nanocrystallites [J].
Dabbousi, BO ;
RodriguezViejo, J ;
Mikulec, FV ;
Heine, JR ;
Mattoussi, H ;
Ober, R ;
Jensen, KF ;
Bawendi, MG .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (46) :9463-9475
[5]   REFERENCE MATERIALS FOR FLUORESCENCE MEASUREMENT [J].
EATON, DF .
PURE AND APPLIED CHEMISTRY, 1988, 60 (07) :1107-1114
[6]   Thiol-capping of CdTe nanocrystals:: An alternative to organometallic synthetic routes [J].
Gaponik, N ;
Talapin, DV ;
Rogach, AL ;
Hoppe, K ;
Shevchenko, EV ;
Kornowski, A ;
Eychmüller, A ;
Weller, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (29) :7177-7185
[7]   Type-II quantum dots: CdTe/CdSe(core/shell) and CdSe/ZinTe(core/shell) heterostructures [J].
Kim, S ;
Fisher, B ;
Eisler, HJ ;
Bawendi, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11466-11467
[8]  
KORNOWSKI A, 2002, J PHYS CHEM B, V106, P7177
[9]   Highly luminescent water-soluble ZnSe nanocrystals and their incorporation in a glass matrix [J].
Li, C. L. ;
Nishikawa, K. ;
Ando, M. ;
Enomoto, H. ;
Murase, N. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 294 (1-3) :33-39
[10]   Surfactant-dependent photoluminescence of CdTe nanocrystals in aqueous solution [J].
Li, CL ;
Murase, N .
CHEMISTRY LETTERS, 2005, 34 (01) :92-93