Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenes

被引：9

作者：

Driess, M ^{[1
]}

Dona, N ^{[1
]}

Merz, K ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lab Inorgan Chem Cluster & Coordinat Chem 1, D-44801 Bochum, Germany

来源：

DALTON TRANSACTIONS | 2004年 / 20期

关键词：

D O I：

10.1039/b411889h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lithiation of the N-benzyl substituted diketoamine ligand PhCH2-N[CH2C(tBu)=O](2) with lithium diisopropylamide (LDA) affords a novel chiral anionic N,O-ligand L; LiL reacts with GeCl2.dioxane to give the corresponding new monomeric germylenes LGeCl and L2Ge.

引用

页码：3176 / 3177

页数：2

共 18 条

[1]

[Anonymous], CAMBRIDGE CRYSTALLOG

[2] ASYMMETRIC DEPROTONATION AND COMPLEXATION REACTIONS MEDIATED BY CHIRAL KETALS AS A ROUTE TO ORTHO-DISUBSTITUTED (ETA-6-ARENE)CR(CO)3 COMPLEXES [J].

AUBE, J ;

HEPPERT, JA ;

MILLIGAN, ML ;

SMITH, MJ ;

ZENK, P .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (13) :3563-3570

[3] Stable germanium analogs of carbenes, imines, ketones, thiones, selones and tellones [J].

Barrau, J ;

Rima, G .

COORDINATION CHEMISTRY REVIEWS, 1998, 178 :593-622

[4] Syntheses and crystal structures of heteroleptic stannylenes and germylenes [J].

Benet, S ;

Cardin, CJ ;

Cardin, DJ ;

Constantine, SP ;

Heath, P ;

Rashid, H ;

Teixeira, S ;

Thorpe, JH ;

Todd, AK .

ORGANOMETALLICS, 1999, 18 (03) :389-398

[5] STUDIES IN STEREOCHEMISTRY .10. THE RULE OF STERIC CONTROL OF ASYMMETRIC INDUCTION IN THE SYNTHESES OF ACYCLIC SYSTEMS [J].

CRAM, DJ ;

ELHAFEZ, FAA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (23) :5828-5835

[6] SUB-VALENT GROUP 4B METAL ALKYLS AND AMIDES .1. SYNTHESIS AND PHYSICAL-PROPERTIES OF KINETICALLY STABLE BIS[BIS(TRIMETHYSILYL)METHYL]-GERMANIUM(II), BIS[BIS(TRIMETHYSILYL)METHYL]-TIN(II), AND BIS[BIS(TRIMETHSILYL)METHYL]-LEAD(II) [J].

DAVIDSON, PJ ;

HARRIS, DH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21) :2268-2274

[7]

DRIESS M, UNPUB CHEM EUR J

[8] CHEMISTRY OF BULKY ALKOXIDES OF BIVALENT GERMANIUM AND TIN - STRUCTURES OF GASEOUS [SN(OBUT)2]2 AND CRYSTALLINE GE(OCBUT3)2 [J].

FJELDBERG, T ;

HITCHCOCK, PB ;

LAPPERT, MF ;

SMITH, SJ ;

THORNE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) :939-941

[9] Novel heteroleptic germanium(II) compounds from [2,4-di-tert-butyl-6-((dimethylamino)methyl)phenyl]germanium chloride:: Synthesis, structure, and derivatization [J].

Jutzi, P ;

Keitemeyer, S ;

Neumann, B ;

Stammler, HG .

ORGANOMETALLICS, 1999, 18 (23) :4778-4784

[10] Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds [J].

Jutzi, P ;

Keitemeyer, S ;

Neumann, B ;

Stammler, A ;

Stammler, HG .

ORGANOMETALLICS, 2001, 20 (01) :42-46

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