Enantioselective catalysis.: Part 119:: New chiral 2-(2-pyridinyl)oxazoline ligands containing an additional optically active substituent in the pyridine system

被引：36

作者：

Brunner, H

Störiko, R

Nuber, B

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(97)00619-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of novel chiral nitrogen ligands and their precursors is described. They consist of an optically active oxazoline bound to pyridine in the 2-position. In addition, another optically active substituent is attached to the pyridine ring. The effect of the two independent stereogenic units in one ligand was studied in the Rh(I)-catalysed enantioselective hydrosilylation of acetophenone with diphenylsilane. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：407 / 422

页数：16

共 32 条

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[Anonymous], CATALYTIC ASYMMETRIC

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