Disiloxanediolates and polyhedral metallasilsesquioxanes of the early transition metals and f-elements

被引：180

作者：

Lorenz, V

Fischer, A

Giessmann, S

Gilje, JW

Gun'ko, Y

Jacob, K

Edelmann, FT

机构：

[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany

[2] James Madison Univ, Dept Chem, Harrisonburg, VA 22807 USA

[3] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland

[4] Univ Halle Wittenberg, Inst Anorgan Chem, Fachbereich Chem, D-06099 Halle, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷

关键词：

disiloxanediolates; metallasilsesquioxanes; silsesquioxanes; lanthanides; actinides; early transition metals;

D O I：

10.1016/S0010-8545(00)00299-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two modern areas of metallasiloxane chemistry are reviewed. The first part deals with the preparation and structural characterization of the first f-element compounds derived from tetraphenylsisiloxanediol. In the second part recent developments in the chemistry of polyhedral metallasilsesquioxanes are surveyed, with special emphasis being placed on early transition metal and f-element derivatives. Also highlighted are applications of these species in catalysis research. (C) 2000 Elsevier Science S.A. AU rights reserved.

引用

页码：321 / 368

页数：48

共 133 条

[1] Modelling the active sites of heterogeneous titanium epoxidation catalysts using titanium silasequioxanes: Insight into specific factors that determine leaching in liquid-phase processes [J].