Oxidative addition of methyl iodide to dinuclear gold(I) amidinate complex: Schmidbaur's breakthrough reaction revisited with amidinates

被引：16

作者：

Abdou, HE ^{[1
]}

Mohamed, AA ^{[1
]}

Fackler, JR ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, Mol Struct & Bonding Lab, College Stn, TX 77843 USA

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2004年 / 59卷 / 11-12期

关键词：

oxidative-addition; gold; amidinate complexes; methyl iodide;

D O I：

10.1515/znb-2004-11-1217

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative-addition of methyl iodide, CH3I, to the dinuclear gold amidinate [Au-2(o-Me-2-form)(2)] in THF generates a metal-metal bonded Au(II) product, formulated as [Au-2(o-Me-2-form)(2)CH3I], in quantitative yield under nitrogen at 0 degreesC and in absence of light. The product is characterized by H-1 NMR, elemental analysis and preliminary X-ray crystallography.

引用

页码：1480 / 1482

页数：3

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