Palladium-copper-DMF complexes involved in the oxidation of alkenes

被引:57
作者
Hosokawa, T [1 ]
Nomura, T
Murahashi, SI
机构
[1] Kochi Univ Technol, Fac Engn, Dept Environm Syst Engn, Kochi 782, Japan
[2] Osaka Univ, Fac Engn Sci, Dept Chem, Toyonaka, Osaka 560, Japan
关键词
palladium; copper chloride; molecular oxygen; DMF; alkene;
D O I
10.1016/S0022-328X(97)00422-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Treatment of PdCl2(MeCN)(2) and CuCl with N,N-dimethylformamide (DMF) under O-2 gives polymeric complex [(PdCl2)(2)CuCl2(DMF)(4)](n) (1) and Pd-Cu heterometallic complex 2 containing O atom derived from molecular oxygen. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:387 / 389
页数:3
相关论文
共 16 条
[1]   TETRACHLOROBIS(2-PYRIDONE)-BIS-(MU-2-2-PYRIDONE)-DICOPPER [J].
BLAKE, AJ ;
WINPENNY, REP .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :799-801
[2]  
CAPDEVIELLE P, 1988, J MOL CATAL, V17, P59
[3]  
CAPDEVIELLE P, 1990, SOC CHEM COMMUN, P565
[4]   MOLECULES WITH AN M4X4 CORE .13. SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE TETRANUCLEAR COMPLEXES [(DENC)CUX]4 (DENC = N,N-DIETHYLNICOTINAMIDE-X = CL, BR, I) AND THE KINETICS OF OXIDATION OF THE CHLORIDE AND BROMIDE BY DIOXYGEN IN APROTIC-SOLVENTS [J].
CHURCHILL, MR ;
DAVIES, G ;
ELSAYED, MA ;
HUTCHINSON, JP ;
RUPICH, MW .
INORGANIC CHEMISTRY, 1982, 21 (03) :995-1001
[5]   IMPROVED PROCEDURES FOR CONVERTING HIGHER ALPHA-OLEFINS TO METHYL KETONES WITH PALLADIUM CHLORIDE [J].
CLEMENT, WH ;
SELWITZ, CM .
JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (01) :241-&
[6]   SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, AND PROPERTIES OF A TETRANUCLEAR COMPLEX FORMED BY OXIDATION OF COPPER(I) CHLORIDE WITH MOLECULAR DIOXYGEN IN N-METHYLPYRROLIDIN-2-ONE - ISOLATION OF A CATALYST FOR OXIDATIVE COUPLING OF PHENOLS BY DIOXYGEN [J].
DAVIES, G ;
ELSHAZLY, MF ;
RUPICH, MW ;
CHURCHILL, MR ;
ROTELLA, FJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (23) :1045-1046
[7]   AQUEOUS SULFOLANE AS SOLVENT FOR RAPID OXIDATION OF HIGHER ALPHA-OLEFINS TO KETONES USING PALLADIUM-CHLORIDE [J].
FAHEY, DR ;
ZUECH, EA .
JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (22) :3276-3277
[8]   PREPARATION AND CHARACTERIZATION OF A PALLADIUM-COPPER HETEROMETALLIC COMPLEX AND ITS CATALYTIC ACTIVITY TOWARDS OXIDATION OF ALKENES [J].
HOSOKAWA, T ;
TAKANO, M ;
MURAHASHI, S ;
OZAKI, H ;
KITAGAWA, Y ;
SAKAGUCHI, K ;
KATSUBE, Y .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (12) :1433-1434
[9]   The first isolation and characterization of a palladium-copper heterometallic complex bearing mu 4-oxo atom derived from molecular oxygen [J].
Hosokawa, T ;
Takano, M ;
Murahashi, SI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (16) :3990-3991
[10]   CHARACTERIZATION OF A NOVEL LOW OXIDATION-STATE TRANSITION-METAL PEROXIDE FROM REACTION OF COPPER(I) CHLORIDE WITH OXYGEN IN PYRIDINE [J].
KRAMER, CE ;
DAVIES, G ;
DAVIS, RB ;
SLAVEN, RW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (15) :606-607