Recent synthesis and transformation of vinylphosphonates

被引：79

作者：

Dembitsky, VM

Al Quntar, AAA

Haj-Yehia, A

Srebnik, M

机构：

[1] Hebrew Univ Jerusalem, Dept Med Chem & Nat Prod, Sch Pharm, IL-91120 Jerusalem, Israel

[2] Hebrew Univ Jerusalem, Dept Pharm, Sch Pharm, IL-91120 Jerusalem, Israel

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2005年 / 2卷 / 01期

关键词：

D O I：

10.2174/1570193052774090

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylphosphonates are an important group of compounds. This review summarizes recent developments in the synthesis and transformations of vinylphosphonates. Owing to the importance of vinylphosphonates, many different synthetic methods have been developed. Especially useful are various organometallic synthetic methods utilizing the chemistry of copper, titanium, zirconium, and lithium, etc. The transformations of vinylphosphonates is also described and include expoxidation, cycloaddition, Suzuki coupling, and Diels-Alder reactions.

引用

页码：91 / 109

页数：19

共 99 条

[71] Hydroboration of unsaturated phosphonic esters: Synthesis of boronophosphonates and trisubstituted vinylphosphonates [J].