π-Stacking interactions in cis-Bisfullerene[60] adducts of 6,13-disubstituted pentacenes

被引：40

作者：

Miller, GP ^{[1
]}

Mack, J ^{[1
]}

Briggs, J ^{[1
]}

机构：

[1] Univ New Hampshire, Dept Chem, Durham, NH 03824 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 25期

关键词：

D O I：

10.1021/ol0064720

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Experimental, molecular modeling, and model compound studies suggest that favorable fullerene[60] pi -stacking interactions in the ground state and in syn-transition states account for the high cis stereoselectivities observed in the reactions between C-60 and 6,13-disubstituted pentacenes.

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页码：3983 / 3986

页数：4

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