Development of β-keto 1,3-dithianes as versatile intermediates for organic synthesis

被引：69

作者：

Gaunt, MJ ^{[1
]}

Sneddon, HF ^{[1
]}

Hewitt, PR ^{[1
]}

Orsini, P ^{[1
]}

Hook, DF ^{[1
]}

Ley, SV ^{[1
]}

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 01期

关键词：

D O I：

10.1039/b208982c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

beta-Keto 1,3-dithianes can be generated by the double conjugate addition of dithiols to propargylic ketones, esters and aldehydes in excellent yields. As masked 1,3-dicarbonyl systems these substrates can be converted to a range of functionalised oxygen-containing heterocycles that can be used in natural product synthesis.

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页码：15 / 16

页数：2

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