Synthesis and characterization of highly ordered functional mesoporous silica thin films with positively chargeable -NH2 groups

被引:77
作者
Liu, NG
Assink, RA
Smarsly, B
Brinker, CJ [1 ]
机构
[1] Univ New Mexico, Dept Chem & Nucl Engn, Albuquerque, NM 87131 USA
[2] Univ New Mexico, Ctr Microengineered Mat, Albuquerque, NM 87131 USA
[3] Sandia Natl Labs, Albuquerque, NM 87106 USA
关键词
D O I
10.1039/b301910a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly ordered mesoporous organic-inorganic hybrid silica thin films with covalently bonded, positively chargeable-NH2 terminal groups were synthesized by evaporation induced self-assembly of tetraethoxysilane, 3-aminopropyltriethoxysilane, and a nonionic surfactant under acid conditions and characterized using TEM, GISAXS, FTIR, SAW-based N-2 sorption, and TGA.
引用
收藏
页码:1146 / 1147
页数:2
相关论文
共 15 条
[1]  
Brinker CJ, 1999, ADV MATER, V11, P579, DOI 10.1002/(SICI)1521-4095(199905)11:7<579::AID-ADMA579>3.0.CO
[2]  
2-R
[3]  
BURKETT SL, 1996, J CHEM SOC CHEM COMM, V11, P1367
[4]   Optically, defined multifunctional patterning of photosensitive thin-film silica mesophases [J].
Doshi, DA ;
Huesing, NK ;
Lu, MC ;
Fan, HY ;
Lu, YF ;
Simmons-Potter, K ;
Potter, BG ;
Hurd, AJ ;
Brinker, CJ .
SCIENCE, 2000, 290 (5489) :107-111
[5]   From structure to function in open ionic channels [J].
Eisenberg, RS .
JOURNAL OF MEMBRANE BIOLOGY, 1999, 171 (01) :1-24
[6]   Computing the field in proteins and channels [J].
Eisenberg, RS .
JOURNAL OF MEMBRANE BIOLOGY, 1996, 150 (01) :1-25
[7]   Synthesis and characterization of ordered organo-silica-surfactant mesophases with functionalized MCM-41-type architecture [J].
Fowler, CE ;
Burkett, SL ;
Mann, S .
CHEMICAL COMMUNICATIONS, 1997, (18) :1769-1770
[8]   Covalent coupling of an organic chromophore into functionalized MCM-41 mesophases by template-directed co-condensation [J].
Fowler, CE ;
Lebeau, B ;
Mann, S .
CHEMICAL COMMUNICATIONS, 1998, (17) :1825-1826
[9]   Template-directed synthesis of bi-functionalized organo-MCM-41 and phenyl-MCM-48 silica mesophases [J].
Hall, SR ;
Fowler, CE ;
Lebeau, B ;
Mann, S .
CHEMICAL COMMUNICATIONS, 1999, (02) :201-202
[10]   Application of large pore MCM-41 molecular sieves to improve pore size analysis using nitrogen adsorption measurements [J].
Kruk, M ;
Jaroniec, M ;
Sayari, A .
LANGMUIR, 1997, 13 (23) :6267-6273