Synthesis and structural investigation of new graphite intercalation compounds containing the perfluoroalkylsulfonate anions C10F21SO3-, C2F5OC2F4SO3-, and C2F5(C6F10)SO3-

被引：13

作者：

Yan, W

Lerner, MM

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

[2] Oregon State Univ, Ctr Adv Mat Res, Corvallis, OR 97331 USA

来源：

CARBON | 2004年 / 42卷 / 14期

基金：

美国国家科学基金会;

关键词：

graphite; intercalation; X-ray diffraction; modeling;

D O I：

10.1016/j.carbon.2004.07.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation of graphite intercalation compounds (GIC's) of three perfluorinated alkylsulfonate anions, C10F21SO3-, C2F5OC2F4SO3- and C2F5(C6F10)SO3- is described for the first time. Pure stage 2 GIC's are obtained by chemical oxidation of graphite with K2MnF6 in a solution containing hydrofluoric and nitric acids for 72 h. One-dimensional electron density maps derived from powder diffraction data are fit to obtain models for the intercalate gallery structures: the structure models provide details on anion concentrations, orientations, and conformations. In all cases, anion bilayers are observed with anion sulfonate headgroups oriented towards graphene sheets. Compared with structures calculated for the isolated anions, the intercalated anion conformations show changes in dihedral angles, involving rotations about C-C or C-O bonds. For the GIC containing C2F5(C6F10)SO3-, the anion conformation change is related to the more efficient packing of anions in the intercalate gallery. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2981 / 2987

页数：7

共 28 条

[1]

Bartlett N, 1982, Intercalation Chemistry Eds, P19

[2] UBER EINE NEUE DARSTELLUNG DES KALIUM-HEXAFLUOROMANGANATS(IV) [J].

BODE, H ;

JENSSEN, H ;

BANDTE, F .

ANGEWANDTE CHEMIE, 1953, 65 (11) :304-304

[3] GRAPHITE SALTS WITH PERFLUOROALKANESULFONIC ACIDS AND ALKANESULFONIC ACIDS [J].

BOEHM, HP ;

HELLE, W ;

RUISINGER, B .

SYNTHETIC METALS, 1988, 23 (1-4) :395-400

[4] ELECTROCHEMICAL EXFOLIATION OF GRAPHITE IN TRIFLUOROACETIC MEDIA [J].

BOURELLE, E ;

DOUGLADE, J ;

METROT, A .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1994, 244 :227-232

[5] STRUCTURES OF MOLECULES AND CRYSTALS OF FLUOROCARBONS [J].

BUNN, CW ;

HOWELLS, ER .

NATURE, 1954, 174 (4429) :549-551

[6] INTERCALATION COMPOUNDS OF GRAPHITE [J].

DRESSELHAUS, MS ;

DRESSELHAUS, G .

ADVANCES IN PHYSICS, 1981, 30 (02) :139-326

[7] GRAPHITE-INTERCALATION CHEMISTRY - AN INTERPRETIVE REVIEW [J].

FORSMAN, WC ;

DZIEMIANOWICZ, T ;

LEONG, K ;

CARL, D .

SYNTHETIC METALS, 1983, 5 (02) :77-100

[8] NEW VARIETY OF GRAPHITE NITRATE [J].

FUZELLIER, H ;

MELIN, J ;

HEROLD, A .

MATERIALS SCIENCE AND ENGINEERING, 1977, 31 :91-94

[9]

HORN D, 1977, MATER SCI ENG, V31, P87, DOI 10.1016/0025-5416(77)90017-9

[10] DO PERFLUORINATED CHAINS ALWAYS HAVE TO BE TWISTED [J].

KNOCHENHAUER, G ;

REICHE, J ;

BREHMER, L ;

BARBERKA, T ;

WOOLLEY, M ;

TREDGOLD, R ;

HODGE, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1619-1620

← 1 2 3 →