Role of single-site catalysts in the hydrogenation of thiophenes: from models systems to effective HDS catalysts

被引:84
作者
Bianchini, C [1 ]
Meli, A [1 ]
Vizza, F [1 ]
机构
[1] CNR, ICCOM, Area Ricerca, I-50019 Florence, Italy
关键词
hydrodesulfurization; hydrogenation; thiophenes; single-site catalysts;
D O I
10.1016/j.jorganchem.2004.05.027
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydrogenation of thiophenes, leading to cyclic thioethers, thiols or hydrocarbons and HA can be achieved by single-site metal catalysts in both homogeneous and heterogeneous phase. An overview of the processes that have provided useful mechanistic information on hydrodesulfurization catalysis, is presented and commented. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:4277 / 4290
页数:14
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