An all-ROMP route to graft copolymers

被引：50

作者：

Hilf, Stefan ^{[1
]}

Kilbinger, Andreas F. M. ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2007年 / 28卷 / 11期

关键词：

graft copolymers; living polymerization; macromonomer; ROMP; OPENING METATHESIS POLYMERIZATION; NORBORNENYL POLYSTYRENE; MACROMONOMERS; ATRP; MACROINITIATOR; COMBINATION;

D O I：

10.1002/marc.200700083

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new versatile synthesis strategy for macromonomers has been developed that uses the living ring-opening metathesis polymerization (ROMP) with commercial Grubbs first generation ruthenium initiators. Homopolymers as well as diblock copolymers were end-functionalized with norbornene derivatives to serve as macromonomers. The graft copolymerization of the macromonomers was also carried out employing ROMP. Well-defined and highly functional graft copolymers are accessible by this new synthetic route.

引用

页码：1225 / 1230

页数：6

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