Opto-electronic multifunctional chiral diamondoid-network coordination polymer: bis{4-[2-(4-pyridyl)ethenyl]benzoato}zinc with high thermal stability

被引:189
作者
Xiong, RG
Zuo, JL
You, XZ [1 ]
Abrahams, BF
Bai, ZP
Che, CM
Fun, HK
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia
[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[4] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
关键词
D O I
10.1039/b004980h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel 8-fold interpenetration diamondoid-like chiral condensed neutral coordination polymer, bis{4-[2-(4-pyridyl)ethenyl]benzoato}zinc [Zn(PEBA)(2)] 1, synthesized by the hydrothermal reaction between Zn(ClO4)(2). 6H(2)O and 4-[2-(4-pyridylethenyl)]benzenecarbonitrile (PEBC), displays very strong blue fluorescent emission and SHG response (ca. 1.5 x that of urea) as well as high thermal stability (up to ca. 430 degrees C).
引用
收藏
页码:2061 / 2062
页数:2
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