Template-controlled face-to-face stacking of olefinic and aromatic carboxylic acids in the solid state

被引：52

作者：

Mei, Xuefeng ^{[1
]}

Liu, Shuanglong ^{[1
]}

Wolf, Christian ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 14期

关键词：

D O I：

10.1021/ol071039c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rigid 1,8-dipyridylnaphthalene template for supramolecular organization of unsaturated dicarboxylic acids in the solid state has been developed. Self-assembly of the template and aromatic dicarboxylic acids generates nondistorted paracyclophane and pyridinophane architectures with perfectly superimposed pi-systems. The dipyridyl template can be used to promote stereoselective solid-state dimerization of olefinic dicarboxylic acids.

引用

收藏

页码：2729 / 2732

页数：4

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