Elucidation of the mechanism of alkene epoxidation by hydrogen peroxide catalysed by titanosilicates: a computational study

被引：64

作者：

Tantanak, D ^{[1
]}

Vincent, MA ^{[1
]}

Hillier, IH ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a801164h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calculated transition states for alkene epoxidation by hydrogen peroxide, catalysed by titanosilicates, predict that it is the oxygen atom of the titanium(IV)-hydroperoxide intermediate closer to the metal centre which attacks the alkene.

引用

页码：1031 / 1032

页数：2

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