Corrosion protection of magnesium alloy AZ31 sheets by spin coating process with poly(ether imide) [PEI]

被引:90
作者
Conceicao, Thiago F. [1 ]
Scharnagl, N. [1 ,2 ]
Blawert, C. [1 ]
Dietzel, W. [1 ]
Kainer, K. U. [1 ]
机构
[1] GKSS Forschungszentrum Geesthacht GmbH, Inst Mat Res, D-21502 Geesthacht, Germany
[2] Charite, Berlin Brandenburg Ctr Regenerat Therapies BCRT, D-13353 Berlin, Germany
关键词
Magnesium; EIS; Polymer coatings; ORGANIC COATINGS; BEHAVIOR; TECHNOLOGIES; MECHANISM; PRECURSOR;
D O I
10.1016/j.corsci.2010.02.027
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
In the present study, the potential of poly(ether imide) as corrosion protective coating for magnesium alloys was evaluated using the spin coating technique. The influence of different parameters on the coating properties was evaluated and the corrosion behaviour of the coatings was investigated using electrochemical impedance spectroscopy. The best corrosion protection was obtained preparing the coatings under N-2 atmosphere, using 15 wt.% solution in N'N'-dimethylacetamide (DMAc) which resulted in a coating of approximately 2 mu m thickness, with an initial impedance of 10(9) Omega cm(2) and of 10(5) Omega cm(2) after 240 h of exposure to a 3.5% NaCl solution. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2066 / 2079
页数:14
相关论文
共 61 条
[1]
ANSDELL DA, 1987, PAINT SURFACE COATIN, pCH10
[2]
The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions [J].
Baril, G ;
Pébère, N .
CORROSION SCIENCE, 2001, 43 (03) :471-484
[3]
A simple method for the preparation of superhydrophobic PVDF-HMFS hybrid composite coatings [J].
Basu, Bharathi Bai J. ;
Paranthaman, Ashok Kumar .
APPLIED SURFACE SCIENCE, 2009, 255 (08) :4479-4483
[4]
BELL, Patent No. 6451383
[5]
The physical chemistry of organic coatings revisited - viewing coatings as a materials scientist [J].
Bierwagen, Gordon .
JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2008, 5 (02) :133-155
[6]
FILM COATING TECHNOLOGIES AND ADHESION [J].
BIERWAGEN, GP .
ELECTROCHIMICA ACTA, 1992, 37 (09) :1471-1478
[7]
Brandrup J., 1999, Polymer Handbook, VII
[8]
A STUDY OF THE BEHAVIOUR OF A THIN SHEET OF MOVING LIQUID [J].
BROWN, DR .
JOURNAL OF FLUID MECHANICS, 1961, 10 (02) :297-&
[9]
Behavior of 3 mol% yttria-stabilized tetragonal zirconia polycrystal film prepared by slurry spin coating [J].
Chen, Kongfa ;
Tian, Yanting ;
Lue, Zhe ;
Ai, Na ;
Huang, Xiqiang ;
Su, Wenhui .
JOURNAL OF POWER SOURCES, 2009, 186 (01) :128-132
[10]
Characterization and corrosion studies of fluoride conversion coating on degradable Mg implants [J].
Chiu, K. Y. ;
Wong, M. H. ;
Cheng, F. T. ;
Man, H. C. .
SURFACE & COATINGS TECHNOLOGY, 2007, 202 (03) :590-598