The rigid, aromatic bis-tridentate bridging ligand tetrapyrido[2,3-a: 3',2'-c:2 ",3 "-h:3''',2'''-j]phenazine (tpp) allowed the preparation of linear, stable bi-and tri-nuclear complexes of ruthenium(II) exhibiting low energy Ru --> tpp MLCT absorptions and a strong electronic coupling in the mixed-valence state.
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Allen C.C., 1967, PROG INORG CHEM, V8, P357, DOI DOI 10.1002/9780470166093.CH6