Bi- and tri-nuclear ruthenium(II) complexes containing tetrapyridophenazine as a rigid bridging ligand

被引:20
作者
Bonhôte, P
Lecas, A
Amouyal, E
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
[3] Univ Paris Sud, CNRS, URA 75, Lab Physicochim Rayonnements, F-91405 Orsay, France
关键词
D O I
10.1039/a709013g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rigid, aromatic bis-tridentate bridging ligand tetrapyrido[2,3-a: 3',2'-c:2 ",3 "-h:3''',2'''-j]phenazine (tpp) allowed the preparation of linear, stable bi-and tri-nuclear complexes of ruthenium(II) exhibiting low energy Ru --> tpp MLCT absorptions and a strong electronic coupling in the mixed-valence state.
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页码:885 / 886
页数:2
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