Advances in layered oxide cathodes for intermediate temperature solid oxide fuel cells

被引:379
作者
Tarancon, Albert [1 ,2 ]
Burriel, Monica [3 ]
Santiso, Jose [4 ]
Skinner, Stephen J. [3 ]
Kilner, John A. [3 ]
机构
[1] CSIC, IMB CNM, Inst Microelect Barcelona, Barcelona 08193, Spain
[2] Catalonia Inst Energy Res IREC, Dept Adv Mat Energy Applicat, Barcelona 08019, Spain
[3] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England
[4] CSIC, Res Ctr Nanosci & Nanotechnol, CSIC ICN, CIN2, Barcelona 08193, Spain
基金
英国工程与自然科学研究理事会;
关键词
EPITAXIAL THIN-FILMS; OXYGEN PERMEATION PROPERTIES; NEUTRON POWDER DIFFRACTION; IONIC-ELECTRONIC CONDUCTIVITY; ELECTRICAL-CONDUCTIVITY; TRANSPORT-PROPERTIES; ELECTROCHEMICAL PERFORMANCE; TRACER DIFFUSION; MIXED CONDUCTOR; SINGLE-CRYSTALS;
D O I
10.1039/b922430k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the context of solid oxide fuel cells (SOFCs) applications, mixed-ionic electronic conductors offer significant advantages over conventional cathodes especially in the intermediate-to-low range of temperatures where the performance of the cathode is of fundamental importance. An increasing number of layered oxide materials have been found to present excellent properties as mixed ionic-electronic conductors. Therefore, considerable efforts have been recently devoted to better understand and evaluate layered ordered structures. This article highlights the most important advances in this topic concentrating on both structural aspects and impact in cathode performance for SOFCs applications.
引用
收藏
页码:3799 / 3813
页数:15
相关论文
共 129 条
[31]   Review on microfabricated micro-solid oxide fuel cell membranes [J].
Evans, Anna ;
Bieberle-Huetter, Anja ;
Rupp, Jennifer L. M. ;
Gauckler, Ludwig J. .
JOURNAL OF POWER SOURCES, 2009, 194 (01) :119-129
[32]   Stability and mixed ionic-electronic conductivity of (Sr,La)(Ti,Fe)O3-δ perovskites [J].
Fagg, DP ;
Kharton, VV ;
Frade, JR ;
Ferreira, AAL .
SOLID STATE IONICS, 2003, 156 (1-2) :45-57
[33]   Defect, protons and conductivity in brownmillerite-structured Ba2In2O5 [J].
Fisher, CAJ ;
Islam, MS .
SOLID STATE IONICS, 1999, 118 (3-4) :355-363
[34]   Solid oxide fuel cell cathodes: Polarization mechanisms and modeling of the electrochemical performance [J].
Fleig, J .
ANNUAL REVIEW OF MATERIALS RESEARCH, 2003, 33 :361-382
[35]   POLARIZATION BEHAVIOR OF YTTRIUM BARIUM COPPER-OXIDE ELECTRODES ON YTTRIA-STABILIZED ZIRCONIA ELECTROLYTES [J].
FLETCHER, JG ;
IRVINE, JTS ;
WEST, AR ;
LABRINCHA, JA ;
FRADE, JR ;
MARQUES, FMB .
MATERIALS RESEARCH BULLETIN, 1994, 29 (11) :1175-1182
[36]   Application of density functional theory to the modeling of the mixed ionic and electronic conductor La2NiO4+δ:: Lattice relaxation, oxygen mobility, and energetics of Frenkel defects [J].
Frayret, C ;
Villesuzanne, A ;
Pouchard, M .
CHEMISTRY OF MATERIALS, 2005, 17 (26) :6538-6544
[37]   Selective spin-state switch and metal-insulator transition in GdBaCo2O5.5 -: art. no. 180405 [J].
Frontera, C ;
García-Muñoz, JL ;
Llobet, A ;
Aranda, MAG .
PHYSICAL REVIEW B, 2002, 65 (18) :1-4
[38]   Selective spin-state and metal-insulator transitions in GdBaCo2O5.5 [J].
Frontera, C ;
García-Muñoz, JL ;
Llobet, A ;
Mañosa, L ;
Aranda, MAG .
JOURNAL OF SOLID STATE CHEMISTRY, 2003, 171 (1-2) :349-352
[39]   Electrical conductivity and oxygen exchange kinetics of La2NiO4+δ thin films grown by chemical vapor deposition [J].
Garcia, Gemma ;
Burriel, Monica ;
Bonanos, Nikolaos ;
Santiso, Jose .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (03) :P28-P32
[40]   ELECTROCHEMICAL OXYGEN INTERCALATION INTO OXIDE NETWORKS [J].
GRENIER, JC ;
WATTIAUX, A ;
DOUMERC, JP ;
DORDOR, P ;
FOURNES, L ;
CHAMINADE, JP ;
POUCHARD, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1992, 96 (01) :20-30