Photocurrent generation at a fullerene self-assembled monolayer-modified gold electrode cast with a polyurethane membrane

被引:51
作者
Enger, O [1 ]
Nuesch, F
Fibbioli, M
Echegoyen, L
Pretsch, E
Diederich, F
机构
[1] Ecole Polytech Fed Lausanne, Lab Phys Solides Semicristallins, CH-1015 Lausanne, Switzerland
[2] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland
[3] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA
关键词
D O I
10.1039/b005642l
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two photoelectrochemical cells based on C-60-SAM-modified gold electrodes have been fabricated and their photoelectric responses with Ar- or O-2-saturated electrolyte investigated. High quantum yields under visible light illumination and without an external electron sacrificer were observed. A new approach consisting of casting an ion-selective polyurethane membrane on the C-60-SAM leads to improved stability of the photocurrent generation.
引用
收藏
页码:2231 / 2233
页数:3
相关论文
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