Nitrosyl transfer from manganese to iron in tropocoronand complexes

被引：21

作者：

Franz, KJ ^{[1
]}

Lippard, SJ ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 16期

关键词：

D O I：

10.1021/ic000360n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nitrosyl transfer reaction is described in which the NO ligand from [Mn(NO)(TC-5,5)] quantitatively transfers to [Fe(TC-5,5)] to form [Fe(NO)(TC-5,5)]. The reaction was monitored by in situ IR spectroscopy to reveal data consistent with NO dissociation from Mn prior to interaction with Fe. [GRAPHICS]

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页码：3722 / +

页数：3

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