Spontaneous aldol and Michael additions of simple enoxytrimethylsilanes in DMSO

被引：43

作者：

Génisson, Y

Gorrichon, L

机构：

[1] CNRS, F-31062 Toulouse 04, France

[2] Univ Toulouse 3, F-31062 Toulouse 04, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 25期

关键词：

Mukaiyama reaction; aldol addition; Michael additions; enoxysilanes; solvent effect;

D O I：

10.1016/S0040-4039(00)00725-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Activation of simple trimethylsilyl ketene acetals by dipolar aprotic solvents has been evidenced, allowing efficient solvent assisted aldol and Michael additions under extremely simple, mild and metal free conditions. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4881 / 4884

页数：4

共 22 条

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