Ferroelectric phases in a chiral bent-core smectic liquid crystal: Dielectric and optical second-harmonic generation measurements

被引:82
作者
Gorecka, E
Pociecha, D
Araoka, F
Link, DR
Nakata, M
Thisayukta, J
Takanishi, Y
Ishikawa, K
Watanabe, J
Takezoe, H
机构
[1] Univ Warsaw, Dept Chem, PL-02089 Warsaw, Poland
[2] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
来源
PHYSICAL REVIEW E | 2000年 / 62卷 / 04期
关键词
D O I
10.1103/PhysRevE.62.R4524
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We report unambiguous evidence for ferroelectricity in a chiral bent-core liquid crystal. This evidence includes (i) a single current peak in the polarization reversal current, (ii) a strong dielectric response that is suppressed by applying a bias electric field, and (iii) strong optical second-harmonic generation in the absence of electric field even at normal incidence. We propose a phase structure that is anticlinic in tilt and ferroelectric in polar order, i.e., smectic-CAPF*.
引用
收藏
页码:R4524 / R4527
页数:4
相关论文
共 19 条
[1]  
BEDAL JP, 1999, MOL CRYST LIQ CRYST, V332, P163
[2]   Structure and properties of liquid crystalline phases formed by achiral banana-shaped molecules [J].
Diele, S ;
Grande, S ;
Kruth, H ;
Lischka, CH ;
Pelzi, G ;
Weissflog, W ;
Wirth, I .
FERROELECTRICS, 1998, 212 (1-4) :169-177
[3]   Spontaneous formation of macroscopic chiral domains in a fluid smectic phase of achiral molecules [J].
Link, DR ;
Natale, G ;
Shao, R ;
Maclennan, JE ;
Clark, NA ;
Korblova, E ;
Walba, DM .
SCIENCE, 1997, 278 (5345) :1924-1927
[4]   Antiferroelectricity and chiral order in new liquid crystals of nonchiral molecules studied by optical second harmonic generation [J].
Macdonald, R ;
Kentischer, F ;
Warnick, P ;
Heppke, G .
PHYSICAL REVIEW LETTERS, 1998, 81 (20) :4408-4411
[5]  
MEYER RB, 1975, J PHYS LETT-PARIS, V36, pL69, DOI 10.1051/jphyslet:0197500360306900
[6]  
NAKATA M, UNPUB
[7]   Distinct ferroelectric smectic liquid crystals consisting of banana shaped achiral molecules [J].
Niori, T ;
Sekine, T ;
Watanabe, J ;
Furukawa, T ;
Takezoe, H .
JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (07) :1231-1233
[8]  
Pelzl G, 1999, ADV MATER, V11, P707, DOI 10.1002/(SICI)1521-4095(199906)11:9<707::AID-ADMA707>3.0.CO
[9]  
2-D
[10]   Structural and electro-optical investigations of the smectic phase of chlorine-substituted banana-shaped compounds [J].
Pelzl, G ;
Diele, S ;
Grande, S ;
Jákli, A ;
Lischka, C ;
Kresse, H ;
Schmalfuss, H ;
Wirth, I ;
Weissflog, W .
LIQUID CRYSTALS, 1999, 26 (03) :401-413